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Non-enzymatic glutathionylation occur mostly during oxidative stress when GSH/GSSG is ~1 and levels of ROS are high
In addition, Chen et al
High Dose Glutathione Drip: The Ultimate Detox for Your Body and Skin Glutathione, often called the master antioxidant, is a naturally occurring molecule in the body that plays a critical role in detoxifying cells and protecting against oxidative stress
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