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Structure visualization and analyses were carried out with UCSF Chimera (version 1.11.2) 88 , UCSF ChimeraX (version 1.7.1) 91 and PyMOL (version 3.0.3

For the GSSCys assays, either GSH was varied between 50 M and 2.0 mM at fixed GSSCys concentrations (25, 50, 100 and 150 M) or GSSCys was varied between 25 and 200 M at fixed concentrations of GSH (0.05, 0.1, 0.2, 0.3 and 1.0 mM for ScGrx7 or 0.3, 0.5, 1.0 and 2.0 mM for PfGrx)