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doi: 10.1002/eji.201343316 168 HashimotoAHayashiIMurakamiYSatoYKitasatoHMatsushitaRet al
N-terminal acetylation, the Nle 4 substitution (methionine replaced by norleucine, oxidation-resistant), the D-Phe 7 substitution (stereochemical inversion resistant to proteolysis) and lactam cyclization are the four pharmacochemical innovations that transform alpha-MSH's 2-5 minute half-life into a multi-hour half-life
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