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I actually had a patient, this was an amazing story, she was about to go get a knee replacement surgery

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For example, if you find that your urine has a very high concentration of glutathione metabolites, it means that you dont produce enough, or that you have a deficiency of the starting amino acids, such as cysteine

Covalent/irreversible inhibitors target the redox/catalytic apparatus of TGR with almost no recognition elements that give affinity and selectivity for TGR over off-targets and the cellular redox apparatus resulting in undesirable cross-reactions and low specificity in vivo 25